A Singularity inside a Singularity; Splitting a water drop during pinch-off of an oil drop. When a fluid droplet breaks-off from a thinning fluid thread, the thickness of the fluid neck becomes vanishingly small at the point of snap-off leading to a singularity. The snap-off mechanism is driven by surface tension forces - surface tension reduces the surface area by decreasing the thickness of the fluid thread.
Making Foam from Monodispersed Bubbles.Foams are trapped pockets of gas in liquids or solids; their structure is a constant source of fascination to almost everyone- from scientists, engineers, chefs and baristas to young children playing with soap bubbles. What is the optimal shape of bubbles in a foam if all the bubbles have the same volume? Lord Kelvin, in 1887, was the first to propose this question as a way to understand perhaps the simplest possible foam structure by determining the lowest energy state of a foam with bubbles having identical volumes. This 3D puzzle was solved computationally in 1994 by Weaire and Phelan and, several years later, it was experimentally realized by Gabbrielli, Meagher, Weaire, Brakke, andHutzler; the resulting bubble structures are not only not simple, they are also asymmetric.
Here we show the formation of a two dimensional foam. The pockets of gas are encapsulated in a thin, flexible shell of nanoparticles and toluene and placed on a glass slide after being generated from a microfluidic device. The liquid shell solidifies over time causing the foam to transition from a liquid to solid structure.
As the shells of the bubbles come into contact with each other, they transition from spherical shapes to polyhedral shapes. The boundaries between the polyhedral shapes are called Plateau borders. Plateau borders are important for fluid drainage and are used to describe the stability of foams. Heat from a hot air gun causes the expansion of the bubbles. (Gif and bubble credits: L. L. A. Adams)
Self Assembly: Trimers. Microfluidics offers a robust and tunable platform for the generation of new artificial materials that can be soft and squishy or rigid and non-deformable. Three aqueous drops containing either red or blue dye are encapsulated inside an ultra-thin sheath of oil and self-assemble into trimers as seen in the gif above. The drops re-arrange to minimize their interfacial energy. The core water drops maintain their spherical shape because the surface tension of water is much higher than the surface tension of the surrounding oil. Other shapes are also possible. (Gif and Trimer Credit: L. L. A. Adams)
Controlled Release. Double emulsions, drops inside of drops, are useful as carriers of drugs and other macromolecules. The mechanical properties of the shells, such as their elasticity, permeability and selectivity, are tunable using different material compositions during their microfluidic production. Here we show a microcapsule with a bio-compatible wax shell composed of different triglycerides. As the shell is heated, the wax shell melts and expands releasing cargo containing different aqueous drops as seen in the gif above. (Gif and emulsion credit: L. L. A. Adams)
Swimming Micron-size Robots? Flowbots?These cylindrically-shaped double emulsions, drops inside of drops, wiggle and buckle after they detach from the nozzle and flow through a microfluidic capillary device. Our goal is to utilize them to detect and cure diseases in the human body, like something from the science fiction movie Fantastic Voyage, by loading them with drugs and sensors. (Flowbots and gif credit: L. L. A. Adams; you tube video here)
Monodispersed Multi-Component Double Emulsions. These drops inside of drops are generated using glass microfluidics. By controlling the stoichiometric ratio of different inner drops and housing reagents separately inside, chemical reactions inside of drops can be triggered with temperature using a temperature sensitive shell or with pressure using an elastic shell. (Soft Matter, Image credit: L. L. A. Adams)
Blowing bubbles: Encapsulating gas inside drops with microfluidic technology. These bubbles are remarkably stable, lasting more than 6 months since the outer shell becomes rigid with solvent evaporation. These bubbles are used for acoustic contrast measurements. (Gif credit: L. L. A. Adams)
Dimers with soft, liquid interfaces. Not all double emulsions, drops inside of drops, are spherical. When microfluidic conditions are right, it is possible to make two component dimers in large quantities. The two inner drops are water, dyed two different colors, and the outer drop is an ultra-thin layer of oil. If you look closely you can see satellite drops trailing the dimers. These satellite drops are composed of oil and surfactants and are a result of the pinch-off of the double emulsion from the injection capillary. The two inner drops do not coalesce with each other and are very stable as a result of the ultra-thin layer of oil and surfactants. The ultra-thin layer of oil mechanically stabilizes the drops by the lubrication effect. (Video credit: L. L. A. Adams)
Triggerable temperature sensitive microcapsules. Controlled coalescence of inner drops inside double emulsions, drops inside of drops, is useful for triggering chemical reactions inside drops with the outer drop serving as a reaction vessel. Using double emulsions as micro-reactors is one of our reasons for encapsulating different types of inner drops inside another drop.
Coalescence of inner drops is triggered with heat from a heat gun as seen in this video. The outer drop is made of wax using a melt emulsification technique. As the wax melts, the inner aqueous droplets are free to rotate and move around until they come into contact with one another. Prior to drops coalescing, a small bridge is formed between drops. This is noticeable in the video. The video is taken with a high speed camera and played back at a much slower rate. (Credits: L. L. A. Adams , Soft Matter)
Another squishy bubble. This double emulsion has a gas core and a polymer shell. It was generated using microfluidic techniques. By compressing the double emulsion between two glass slides, we can test its elasticity as shown in the video above. (Credits: L. L. A. Adams)
Pressure responsive microbubbles. Deforming air bubbles is easy with compression, but their life time is very short because compression forces are strong enough to overcome surface tension forces causing bubbles to burst. One way to increase their lifetime is to encapsulate air bubbles in a protective polymer shell using microfluidics. By sandwiching ‘polymer encapsulated bubbles’ in between two glass slides and pressing on the top slide, we demonstrate not only its elasticity, but also its robustness as seen in the video above and also seen here. We can tune the elastic properties of the shell by adding nanoparticles to the polymer matrix. Moreover, a shell with only nanoparticles and no polymers is extremely rigid and easily cracks. (Gif credit: L. L. A. Adams)
Chiral Double Emulsions. Double emulsions with four different components are generated with microfluidics as are their isomers to form enantiomers. Pairs of stereoisomer emulsions that are enantiomers are mirror images of each other but they cannot be superimposed onto each other. Moreover, since the shape, size, and composition are control parameters that govern the properties of these structures and their subsequent self-assembly into larger aggregates, using microfluidics to tune these parameters facilitates a rich area of study of their bulk properties as well as their properties at the single emulsion level. For example, while the optical properties of chiral molecules have been extensively investigated and remarkably demonstrate the ability to rotate plane polarized light, no one knows how chiral double emulsions will interact with microwaves. (Image credit: L. L. A. Adams)
These boots are made for obstructing. While generating double emulsions using glass capillaries looks easy, there are actually a few tricks for making it work. One is the careful alignment between the injection and collection glass capillaries. The other is preventing the wrong fluids from wetting the surfaces of the capillaries. Here we show wetting in the form of an ‘oil boot’ that pushes down on water-oil- water double emulsions as they exit the device; this is seen in the video.
Wetting can interfere with the flow dynamics making it impossible to generate double emulsions or very difficult to produce complex double emulsions. How fluids wet the glass capillary surface depends on the interaction between the fluids with glass. Often we treat the surface of the capillaries with hydrophobic or hydrophilic silanes; the choice of silanes we use depends on whether or not we are making water-oil-water or oil-water-oil double emulsions. And with some fluids, particularly when encapsulating gas, it is better not to treat the capillaries at all. (Video credit: L. L. A. Adams)